Episode 4 is out of sync at the end because it has a 24fps section that runs at 30fps. I made a timecode file for it here: https://nofile.io/f/wyaPVgaQwzx/mkv-timecodesfile.txt
Remux episode 4 with it as the video's timestamp file in mkvtoolnix GUI.
If that dies you can just make a text file with:
Assume 29.970030
33122,33558,23.976024
And there's your timecode file.
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kuchikirukia
kuchikirukia
babaob
tonikaku
shark_bloody
Sts115